Preheat your oven to 350 degrees F. Generously grease your skull pan with magic cake goop or spray it with nonstick baking spray.
In a mixing bowl, whisk together the espresso, Kahlua, melted butter, oil, and cocoa powder. The hot oil enhances the chocolate flavor, while the coffee adds depth. Let sit for 5 minutes to bloom the cocoa.
⅓ cup black cocoa powder, ½ cup unsalted butter, ½ cup vegetable oil, ½ cup instant espresso, ½ cup coffee liqueur
In a large mixing bowl, whisk together all the dry ingredients until well combined.
2 cups all purpose flour, 2 cups granulated sugar, 1 teaspoon baking soda, 1 teaspoon kosher salt
Gradually whisk the chocolate-oil-coffee mixture into the dry ingredients. Then mix in the buttermilk, eggs, and vanilla extract until fully incorporated.
½ cup full fat buttermilk, 2 large eggs, 1 teaspoon vanilla extract
Pour the batter into the prepared skull pan (it will be liquidy!). Place the pan on a baking sheet and bake the cake for 50-55 minutes, or until a cake tester or toothpick inserted into the center comes out clean. For best results, use an instant-read thermometer; the cake should reach an internal temperature of 205-210°F.
Remove the skull cake from the oven; allow the cake to cool in the pan for 10 minutes. Carefully remove the skull halves from the pans and transfer them to a wire rack, cooling completely face-side up.